The effects of growth conditions on the surface properties and photocatalytic activities of anatase TiO films prepared via electrochemical anodizing and annealing methods

In the present work, nanostructured TiO films were prepared by electrochemical anodization process of titanium in fluoride-containing electrolytes using an innovative approach. After anodization, the TiO films were annealed at 480 °C for 2 h in air in order to acquire anatase phase transformation and increase its crystallinity. The effects of anodization voltage, electrolyte concentration and anodization time on the formation of TiO films and the photocatalytic degradation of methylene blue (MB) were discussed in details. The phase structure and surface morphology of the samples characterized by means of X-ray diffraction and scanning electron microscope. The as-prepared nanostructured TiO film anodized in 0.5% HF electrolyte at 15 V for 240 min showed excellent photocatalytic degradation of MB and is promising for environmental purification.