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Effect of temperature on the behavior of osmotic and activity coefficients of amides in aqueous solutions

Journal of Thermal Analysis and Calorimetry, ISSN: 1388-6150, Vol: 92, Issue: 3, Page: 705-710
2008
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The osmotic coefficients of acetamide, propionamide and butyramide in water were measured at 293.15, 298.15 and 308.15 K using the isopiestic method. The activity coefficients were calculated for the aliphatic amides and the pairwise free energy coefficients for solute-solute interactions were determined according to the McMillan-Mayer theory. The osmotic and activity coefficients of amides are discussed in terms of solute-solute interactions. © 2008 Springer Science+Business Media, LLC.

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