Thermal behavior, compatibility study and safety assessment of diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX)
Journal of Thermal Analysis and Calorimetry, ISSN: 1588-2926, Vol: 139, Issue: 3, Page: 1771-1777
2020
- 19Citations
- 6Captures
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Article Description
Thermal decomposition study of diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX) was investigated by using DSC. The result showed that ABTOX is less thermal sensitive than TKX-50. The kinetic parameters (E = 139.82 kJ mol and lgA = 12.75 s) for thermal decomposition reaction of ABTOX were obtained. The compatibility of ABTOX with 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX), 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaza-isowurtzitane (CL-20), 3-nitro-1,2,4-triazol-5-one (NTO), 1,1-diamino-2,2-dinitroethene (FOX-7), 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105), aluminum powder (Al), Estane-TPU-5702 and two kinds of fluoropolymers (F-2311 and F-2603) were evaluated by using DSC. The results showed that CL-20/ABTOX, FOX-7/ABTOX and F-2603/ABTOX were exhibiting good compatibility and RDX/ABTOX and Al/ABTOX had moderate compatibility. In addition, the compatibility of ABTOX with Estane-TPU-5702 and F-2311 was not good. HMX/ABTOX, NTO/ABTOX and LLM-105/ABTOX had poor compatibility. Furthermore, the self-accelerating decomposition temperature was calculated to be 152 °C and 150 °C in commercial wooden and PE cylinder, respectively.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85069901582&origin=inward; http://dx.doi.org/10.1007/s10973-019-08605-x; http://link.springer.com/10.1007/s10973-019-08605-x; http://link.springer.com/content/pdf/10.1007/s10973-019-08605-x.pdf; http://link.springer.com/article/10.1007/s10973-019-08605-x/fulltext.html; https://dx.doi.org/10.1007/s10973-019-08605-x; https://link.springer.com/article/10.1007/s10973-019-08605-x
Springer Science and Business Media LLC
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