Thermal behavior of the products of 2-chloro-2-propen-1-ol oligomerization
Journal of Thermal Analysis and Calorimetry, ISSN: 1588-2926, Vol: 146, Issue: 4, Page: 1623-1627
2021
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Article Description
The thermal stability of the oligomers obtained by using 2-chloro-2-propen-1-ol as the monomer has been studied. The oligomers were synthesized using chromium(III) and oxovanadium(IV) complexes as the catalysts after activation by modified methylaluminoxane (MMAO-12). The complexes used as the catalysts were polycarboxylate complex compounds of oxovanadium(IV) and chromium(III). The studies have been conducted by two methods: thermal gravimetry and differential scanning calorimetry. The obtained results allow to determine the glass transition temperatures and thermal stability of the oligomers depending on the central catalyst cation Cr and V.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85089489200&origin=inward; http://dx.doi.org/10.1007/s10973-020-10168-1; https://link.springer.com/10.1007/s10973-020-10168-1; https://link.springer.com/content/pdf/10.1007/s10973-020-10168-1.pdf; https://link.springer.com/article/10.1007/s10973-020-10168-1/fulltext.html; https://dx.doi.org/10.1007/s10973-020-10168-1; https://link.springer.com/article/10.1007/s10973-020-10168-1
Springer Science and Business Media LLC
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