Transition temperature reduction for CdS nanoparticles under high pressure
Journal of Nanoparticle Research, ISSN: 1388-0764, Vol: 13, Issue: 12, Page: 6563-6568
2011
- 5Citations
- 10Captures
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Article Description
The structure transition of nanoparticles has a significant effect on their practical applications. In this study, the transition temperature of CdS nanoparticles with the size of 3-5 nm from sphalerite to wurtzite structure is significantly reduced to 150 °C under a high pressure of 1 GPa, much lower than that 300-400 °C for CdS nanoparticles and 600 °C for bulk CdS under room pressure. The lower transition temperature leads to an ultrafine grain size d = 5 nm for the formed wurtzite phase as compared with that d = 33 nm yielded under room pressure with a similar transition volume fraction of*80%. The underlying physical mechanism is discussed. © 2011 Springer Science+Business Media B.V.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84857053295&origin=inward; http://dx.doi.org/10.1007/s11051-011-0562-1; http://link.springer.com/10.1007/s11051-011-0562-1; http://link.springer.com/content/pdf/10.1007/s11051-011-0562-1; http://link.springer.com/content/pdf/10.1007/s11051-011-0562-1.pdf; http://link.springer.com/article/10.1007/s11051-011-0562-1/fulltext.html; http://www.springerlink.com/index/10.1007/s11051-011-0562-1; http://www.springerlink.com/index/pdf/10.1007/s11051-011-0562-1; https://dx.doi.org/10.1007/s11051-011-0562-1; https://link.springer.com/article/10.1007/s11051-011-0562-1
Springer Science and Business Media LLC
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