Zinc supported on alkaline activated HZSM-5 for aromatization reaction
Reaction Kinetics, Mechanisms and Catalysis, ISSN: 1878-5204, Vol: 125, Issue: 2, Page: 1085-1098
2018
- 15Citations
- 7Captures
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Article Description
The parent HZSM-5 was activated by NaOH solution with different concentration to obtain a series of alkaline activated HZSM-5-m (m denotes the concentration of NaOH). Zn (2 wt%) was supported on HZSM-5 and HZSM-5-m via the impregnation method by using Zn(NO)·6HO as a precursor. The materials were systematically characterized by XRD, FT-IR, N adsorption–desorption at low temperature, and NH-TPD techniques. It was found that the acidity and textural properties of the HZSM-5-m could be adjusted by altering the concentration of NaOH. Moreover, the amount and distribution of acidity and the pore structure of catalyst had a significantly influence on heptane conversion and aromatics content. As a result, an efficient Zn/HZSM-5-m catalyst for aromatization reaction was obtained by changing the concentration of NaOH.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85047660017&origin=inward; http://dx.doi.org/10.1007/s11144-018-1426-9; http://link.springer.com/10.1007/s11144-018-1426-9; http://link.springer.com/content/pdf/10.1007/s11144-018-1426-9.pdf; http://link.springer.com/article/10.1007/s11144-018-1426-9/fulltext.html; https://dx.doi.org/10.1007/s11144-018-1426-9; https://link.springer.com/article/10.1007/s11144-018-1426-9
Springer Science and Business Media LLC
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