Preparation of facile separable homogeneous Rhodium catalyst and its application for the catalytic hydrogenation of nitrile butadiene rubber and styrene-butadiene rubber
Research on Chemical Intermediates, ISSN: 1568-5675, Vol: 43, Issue: 7, Page: 3651-3662
2017
- 14Citations
- 5Captures
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Article Description
Poly(propylene imine) dendrimer (G2-PPI) terminated by nitrogen-containing triolefinic macrocycle on the periphery (G2-M) was synthesized by a nucleophilic substitution reaction. The structure and composition of G2-M were characterized by FT-IR, H-NMR and elemental analysis. The Rh dendrimer-stabilized catalyst (G2-M(Rh)) was prepared by utilizing G2-M as stabilizer and analyzed by UV–Vis spectroscopy, H-NMR spectrometry, XPS and XRD. G2-M(Rh) demonstrates excellent catalytic activity and selectivity for the hydrogenation of nitrile-butadiene rubber (NBR) and styrene-butadiene rubber (SBR), and Rh residue contents for HNBR and HSBR are only 35 and 13 ppm, respectively, without any post treatment.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85007442863&origin=inward; http://dx.doi.org/10.1007/s11164-016-2838-7; http://link.springer.com/10.1007/s11164-016-2838-7; http://link.springer.com/content/pdf/10.1007/s11164-016-2838-7.pdf; http://link.springer.com/article/10.1007/s11164-016-2838-7/fulltext.html; https://dx.doi.org/10.1007/s11164-016-2838-7; https://link.springer.com/article/10.1007/s11164-016-2838-7
Springer Nature
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