Green and convenient protocols for the efficient reduction of nitriles and nitro compounds to corresponding amines with NaBH in water catalyzed by magnetically retrievable CuFeO nanoparticles
Research on Chemical Intermediates, ISSN: 1568-5675, Vol: 45, Issue: 6, Page: 3329-3357
2019
- 45Citations
- 34Captures
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Article Description
In this study, firstly, CuFeO nanoparticles were prepared by a simple operation. The structure of the mentioned nanoparticles was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, trans-mission electron microscopy, energy-dispersive X-ray spectroscopy, inductively coupled plasma-optical emission spectrometry, vibrating sample magnetometer and also Brunauer–Emmett–Teller and Barrett–Joyner–Halenda analyses. The prepared magnetically copper ferrite nanocomposite was successfully applied as a simple, cost-effective, practicable, and recoverable catalyst on the green, highly efficient, fast, base-free, and ligand-free reduction of nitriles and also on the affordable and eco-friendly reduction of nitro compounds with the broad substrate scope to the corresponding amines with NaBH in water at reflux in high to excellent yields.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85063045079&origin=inward; http://dx.doi.org/10.1007/s11164-019-03794-4; http://link.springer.com/10.1007/s11164-019-03794-4; http://link.springer.com/content/pdf/10.1007/s11164-019-03794-4.pdf; http://link.springer.com/article/10.1007/s11164-019-03794-4/fulltext.html; https://dx.doi.org/10.1007/s11164-019-03794-4; https://link.springer.com/article/10.1007/s11164-019-03794-4
Springer Science and Business Media LLC
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