Two-dimensional Zn coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure
Russian Chemical Bulletin, ISSN: 1573-9171, Vol: 72, Issue: 1, Page: 177-183
2023
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Article Description
The reaction of zinc(II) nitrate with 5-iodoisophthalic acid (5-I-IPAH) in N,N-dimethylformamide afforded the layered coordination polymer {Zn(5-I-IPA)}(1). The structure of 1 was determined by single-crystal X-ray diffraction. The phase purity of 1 was confirmed by powder X-ray diffraction. The molecular electrostatic potentials of iodine atoms, which characterize their ability to form a halogen bond, were determined by quantum chemical calculations.
Bibliographic Details
Springer Science and Business Media LLC
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