Effect of the Composition and Post-Synthesis Heat Treatment on the Electrochemical Characteristics of Polypyrrole/VO Nanocomposites Prepared by a Mechanochemical Method
Theoretical and Experimental Chemistry, ISSN: 1573-935X, Vol: 51, Issue: 3, Page: 163-169
2015
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Article Description
Effects were shown for the composition and post-synthesis heat treatment in an oxygen atmosphere on the electrochemical properties of nanocomposites derived from polypyrrole (PPy) and a VO xerogel with host–guest structure. PPyVO was found to have the highest specific discharge capacity of about 290 mA·h/g and high stability upon prolonged charge-discharge cycling among the PPyVO nanocomposites prepared (where x = 0.1, 0.05, 0.025). Post-synthesis heat treatment in an oxygen atmosphere leads to oxidation of the reduced portion of the inorganic nanocomposite component and nanostructurization of the composite with formation of nanofibers that facilitate a considerable increase in the specific capacity and stability upon cycling.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84939236315&origin=inward; http://dx.doi.org/10.1007/s11237-015-9411-0; http://link.springer.com/10.1007/s11237-015-9411-0; http://link.springer.com/content/pdf/10.1007/s11237-015-9411-0; http://link.springer.com/content/pdf/10.1007/s11237-015-9411-0.pdf; http://link.springer.com/article/10.1007/s11237-015-9411-0/fulltext.html; https://dx.doi.org/10.1007/s11237-015-9411-0; https://link.springer.com/article/10.1007/s11237-015-9411-0
Springer Science and Business Media LLC
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