Manganese(II), cobalts(II) and nickel(II) complexes of tris(2-pyridyl) phosphine and their catalytic activity toward oxidation of tetralin
Transition Metal Chemistry, ISSN: 0340-4285, Vol: 37, Issue: 1, Page: 63-69
2012
- 13Citations
- 12Captures
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Article Description
Monomeric Mn , Co and Ni complexes of tris(2-pyridyl)phosphine (P(2-py) were synthesized through the reaction of the hydrated metal(II) chlorides with P(2-py) in near-quantitative yields. The solid-state structure of the Mn complex was determined by singlecrystal X-ray diffraction. All three complexes were tested as homogeneous catalysts for the oxidation of tetralin to α-tetralone with tert-butyl hydroperoxide (TBHP) as oxidant. The influences of temperature, solvent, catalyst molar ratio and time of the reaction on the catalyzed reactions were investigated. © Springer Science+Business Media B.V. 2011.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84861836446&origin=inward; http://dx.doi.org/10.1007/s11243-011-9558-z; http://link.springer.com/10.1007/s11243-011-9558-z; http://link.springer.com/content/pdf/10.1007/s11243-011-9558-z; http://link.springer.com/content/pdf/10.1007/s11243-011-9558-z.pdf; http://link.springer.com/article/10.1007/s11243-011-9558-z/fulltext.html; https://dx.doi.org/10.1007/s11243-011-9558-z; https://link.springer.com/article/10.1007/s11243-011-9558-z; http://www.springerlink.com/index/10.1007/s11243-011-9558-z; http://www.springerlink.com/index/pdf/10.1007/s11243-011-9558-z
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