Synthesis, spectroscopy and crystal structures of three diiron ethanedithiolate complexes with tertiary phosphine ligands: vinyldiphenylphosphine, 4-(dimethylamino)phenylphosphine or bis(4-methoxyphenyl)phenylphosphine
Transition Metal Chemistry, ISSN: 1572-901X, Vol: 44, Issue: 1, Page: 5-10
2019
- 1Citations
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Metrics Details
- Citations1
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Article Description
Three diiron ethanedithiolate complexes of tertiary phosphine ligands, namely (µ-SCH CH S-μ)Fe (CO) L [L = Ph PCH=CH , 2; Ph P(C H NMe -4), 3; PhP(C H OMe-4) , 4], were synthesized by carbonyl substitution of the parent complex (µ-SCH CH S-μ)Fe (CO) (1) with the corresponding monophosphine ligands in the presence of Me NO·2H O as a decarbonylating agent. Complexes 2‒4 were characterized by elemental analysis and spectroscopy; in addition, their molecular structures were determined by X-ray crystallography.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85050344472&origin=inward; http://dx.doi.org/10.1007/s11243-018-0263-z; http://link.springer.com/10.1007/s11243-018-0263-z; http://link.springer.com/content/pdf/10.1007/s11243-018-0263-z.pdf; http://link.springer.com/article/10.1007/s11243-018-0263-z/fulltext.html; https://dx.doi.org/10.1007/s11243-018-0263-z; https://link.springer.com/article/10.1007/s11243-018-0263-z
Springer Science and Business Media LLC
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