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Metal-Catecholate Frameworks as Solid Basic Catalysts

Topics in Catalysis, ISSN: 1022-5528, Vol: 59, Issue: 19-20, Page: 1757-1764
2016
  • 6
    Citations
  • 0
    Usage
  • 10
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    6
    • Citation Indexes
      6
  • Captures
    10

Article Description

Metal catecholate frameworks, based on 2,3,6,7,10,11-hexahydroxytriphenylene and bivalent metal ions (Ni, Cu, Zn, Mg, Ca, Sr and Ba) were synthesized, characterized with powder X-ray diffraction and N physisorption, and evaluated as catalysts in Knoevenagel condensation and Michael addition reactions. The large number of catecholate oxygen atoms in these materials resulted in a high catalytic activity which was shown to be a function of both the porosity of the material and the electronegativity of the metal ion.

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