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Standard molar enthalpy of formation of uniform CdMoO nano-octahedra

Chinese Science Bulletin, ISSN: 1001-6538, Vol: 58, Issue: 26, Page: 3208-3212
2013
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Article Description

Controllable synthesis of uniform and single-crystalline CdMoO nano-octahedra has been successfully realized at large-scale by a facile reverse-microemulsion route at room temperature. The structures, compositions and morphologies of the as-prepared products were characterized in detail by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), respectively. According to the thermochemical cycle, the relationship between the standard molar enthalpy of formation of nano-CdMoO and bulk CdMoO was proposed for the first time. In combination with micro-calorimetry, the standard molar enthalpies of formation at 298.15 K of as-ynthesized CdMoO nano-octahedra were obtained. © 2013 The Author(s).

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