Iota-carrageenan-based polymer electrolyte: impact on ionic conductivity with incorporation of AmNTFSI ionic liquid for supercapacitor
Ionics, ISSN: 1862-0760, Vol: 25, Issue: 7, Page: 3321-3329
2019
- 26Citations
- 44Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
Green solid polymer electrolytes have drawn attention as multifunctional electrolyte as compared to liquid electrolyte due to their flexibility membranes. In the present work, biodegradable iota-carrageenan polymer has been chosen as the host polymer with magnesium tri-fluromethanesulfonate (MgTf) as the salt. The polymer film was incorporated with methyl-trioctylammonium bis(trifluoromethyl sulfonyl)imide (AmNTFSI) ionic liquid to amplify the ionic conductivity via adding mobile cations and tuning the crystallinity as well as the glass temperature of the polymer. Upon the incorporation of AmNTFSI, the ionic conductivity was remarkably augmented from (1.24 + 0.01) × 10 S cm to the maximum value of (3.20 + 0.01) × 10 S cm at room temperature. The thermal, structural, and temperature dependence conductivity measurements of polymer films (with and without AmNTFSI) have been analyzed, and the performance as the supercapacitor electrolytes has been evaluated.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85060707897&origin=inward; http://dx.doi.org/10.1007/s11581-019-02865-1; http://link.springer.com/10.1007/s11581-019-02865-1; http://link.springer.com/content/pdf/10.1007/s11581-019-02865-1.pdf; http://link.springer.com/article/10.1007/s11581-019-02865-1/fulltext.html; https://dx.doi.org/10.1007/s11581-019-02865-1; https://link.springer.com/article/10.1007/s11581-019-02865-1
Springer Science and Business Media LLC
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