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Electrochemical study of anatase TiO nanotube array electrode in electrolyte based on 1,3-diethylimidazolium bis(trifluoromethylsulfonyl)imide ionic liquid

Ionics, ISSN: 1862-0760, Vol: 25, Issue: 11, Page: 5501-5513
2019
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The density, viscosity and electrical conductivity of ionic liquid 1,3-diethylimidazolium bis(trifluoromethylsulfonyl)imide, (CCimTFSI), and 0.5-M solution of LiTFSI in CCimTFSI were determined at different temperatures. The LiTFSI/CCimTFSI system was tested as a possible electrolyte for lithium-ion batteries by using anatase TiO nanotube array electrode as anode material for the first time. The electrochemical testing has shown not only the improvement of lithium-ion insertion/deinsertion properties by increasing temperature but also the existence of a decomposition of the electrolyte, detecting the change of colour. The decomposition of electrolyte leads to the formation of a film on the surface of the electrode which improves Coulombic efficiency during cycling.

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