On the electrochemical reduction mechanism of CaWO to W powder
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, ISSN: 1073-5615, Vol: 43, Issue: 4, Page: 667-670
2012
- 15Citations
- 14Captures
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Conference Paper Description
The reduction mechanism of CaWO to W in molten eutectic CaCl -NaCl electrolyte has been studied. Cyclic voltammetry and constant potential electrolysis tests were performed to determine the reversible cell potential. Analyses of the experimental results revealed that at least 2.2 V was required to compensate the potentials for the accompanying cell reaction and the electrode polarizations. A cell reaction was proposed by associating the experimental results and the Gibbs energy changes of the possible reactions. © 2012 THE MINERALS, METALS & MATERIALS SOCIETY and ASM INTERNATIONAL.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84865345921&origin=inward; http://dx.doi.org/10.1007/s11663-012-9689-4; https://link.springer.com/10.1007/s11663-012-9689-4; http://www.springerlink.com/index/10.1007/s11663-012-9689-4; http://www.springerlink.com/index/pdf/10.1007/s11663-012-9689-4; https://dx.doi.org/10.1007/s11663-012-9689-4; https://link.springer.com/article/10.1007/s11663-012-9689-4
Springer Science and Business Media LLC
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