Supramolecular structures constructed from three novel rare earth metal complexes
Journal of Chemical Sciences, ISSN: 0973-7103, Vol: 127, Issue: 5, Page: 857-863
2015
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Article Description
Abstract Three rare earth metal supramolecular complexes, {[Tb(L 2 )4](ClO4)3·2H2O(1), [Eu(L 2 )2(H2O)5] (ClO4)3(2) and [Gd(NO3)3(L 2 )2] ·2CH3 CH 2OH(3) (L 2 = 3-Dimethylamino-1-pyridin-2-yl-propenone), have been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The crystal structure analysis reveals that the coordination numbers of three complexes (1-3) are 8, 9 and 10, respectively. Three complexes assembled into 3D frameworks based on C-H ⋯O, O-H ⋯O hydrogen bond linkages. [Figure not available: see fulltext.]
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84938092896&origin=inward; http://dx.doi.org/10.1007/s12039-015-0840-z; http://link.springer.com/10.1007/s12039-015-0840-z; http://link.springer.com/content/pdf/10.1007/s12039-015-0840-z; http://link.springer.com/content/pdf/10.1007/s12039-015-0840-z.pdf; http://link.springer.com/article/10.1007/s12039-015-0840-z/fulltext.html; https://dx.doi.org/10.1007/s12039-015-0840-z; https://link.springer.com/article/10.1007/s12039-015-0840-z
Springer Science and Business Media LLC
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