Modulating the growth of cysteine-capped cadmium sulfide quantum dots with enzymatically produced hydrogen peroxide
Nano Research, ISSN: 1998-0000, Vol: 10, Issue: 6, Page: 1932-1941
2017
- 11Citations
- 12Usage
- 9Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations11
- Citation Indexes11
- CrossRef11
- 11
- Usage12
- Downloads12
- Captures9
- Readers9
Article Description
Cysteine (CSH) readily stabilizes cadmium sulfide quantum dots (CdS QDs) that grow in aqueous buffered solutions. The oxidation of CSH by hydrogen peroxide (HO) at room temperature yields cystine (CSSC), which is less efficient in stabilizing CdS QDs compared to CSH. Herein, we demonstrate that such oxidation causes a decrease in the formation rate of CSH-capped CdS QDs from Cd and S ions. For the first time, we combined the oxidation of CSH with the glucose oxidase (GO)-assisted biocatalytic oxidation of D-glucose, which leads to a buildup of HO in the reaction mixture. The enzymatically modulated in situ growth of CdS QDs was monitored using two techniques: fluorescence spectroscopy and photoelectrochemical (PEC) analysis. This system enables quantification of GO and glucose in human serum. [Figure not available: see fulltext.].
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85013500047&origin=inward; http://dx.doi.org/10.1007/s12274-016-1378-1; http://link.springer.com/10.1007/s12274-016-1378-1; https://dc.tsinghuajournals.com/graphical-abstracts/355; https://dc.tsinghuajournals.com/cgi/viewcontent.cgi?article=1354&context=graphical-abstracts; http://sciencechina.cn/gw.jsp?action=cited_outline.jsp&type=1&id=6013459&internal_id=6013459&from=elsevier; https://dx.doi.org/10.1007/s12274-016-1378-1; https://link.springer.com/article/10.1007/s12274-016-1378-1
Tsinghua University Press
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