RAFT (Co)polymerization of 1,1,1,3,3,3-Hexafluoroisopropyl Acrylate as the Synthesis Technique of Amphiphilic Copolymers
Macromolecular Research, ISSN: 2092-7673, Vol: 29, Issue: 8, Page: 524-533
2021
- 4Citations
- 2Captures
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Article Description
The reversible addition-fragmentation chain transfer (RAFT) polymerization of 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) in the presence of dibenzyl carbonotrithioate (BTC) was studied. The effect of solvent used in polymerization process on kinetic features and molecular-weight characteristics was shown. It turns out that polymerization of HFIPA proceeds in a control mode at any conditions investigated that is confirmed by linear increase of M with the rise of conversion and low values of dispersity (Đ = 1.09–1.3). The location of trithiocarbonate group was estimated both quantum-chemical calculation and experimental methods. Copolymerization monomer pairs of HFIPA-acrylic acid and HFIPA-tert-butyl acrylate in the presence of low molecular (BTC) and polymeric chain transfer agent were investigated. Reactivity ratios of monomers was determined by Fineman-Ross and Kelen-Tudos models. The use of polymeric RAFT agent leads to instance of preferential solvation effect and formation of copolymer with gradient microstructure at final conversion. [Figure not available: see fulltext.].
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85113709739&origin=inward; http://dx.doi.org/10.1007/s13233-021-9066-8; https://link.springer.com/10.1007/s13233-021-9066-8; https://link.springer.com/content/pdf/10.1007/s13233-021-9066-8.pdf; https://link.springer.com/article/10.1007/s13233-021-9066-8/fulltext.html; https://dx.doi.org/10.1007/s13233-021-9066-8; https://link.springer.com/article/10.1007/s13233-021-9066-8
Springer Science and Business Media LLC
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