Nickel-Catalyzed Reductive Couplings
Topics in Current Chemistry, ISSN: 0340-1022, Vol: 374, Issue: 4, Page: 43
2016
- 288Citations
- 89Captures
- 1Mentions
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations288
- Citation Indexes288
- 288
- CrossRef18
- Captures89
- Readers89
- 89
- Mentions1
- News Mentions1
- 1
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Book Chapter Description
The Ni-catalyzed reductive coupling of alkyl/aryl with other electrophiles has evolved to be an important protocol for the construction of C–C bonds. This chapter first emphasizes the recent progress on the Ni-catalyzed alkylation, arylation/vinylation, and acylation of alkyl electrophiles. A brief overview of CO fixation is also addressed. The chemoselectivity between the electrophiles and the reactivity of the alkyl substrates will be detailed on the basis of different Ni-catalyzed conditions and mechanistic perspective. The asymmetric formation of C(sp)–C(sp) bonds arising from activated alkyl halides is next depicted followed by allylic carbonylation. Finally, the coupling of aryl halides with other C(sp)–electrophiles is detailed at the end of this chapter.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84976345139&origin=inward; http://dx.doi.org/10.1007/s41061-016-0042-2; http://www.ncbi.nlm.nih.gov/pubmed/27573395; http://link.springer.com/10.1007/s41061-016-0042-2; https://dx.doi.org/10.1007/s41061-016-0042-2; https://link.springer.com/article/10.1007/s41061-016-0042-2
Springer Nature
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