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Millimeter-wave spectroscopy of the GeF + ion

Chemical Physics Letters, ISSN: 0009-2614, Vol: 171, Issue: 3, Page: 175-180
1990
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Metrics Details

  • Citations
    14
    • Citation Indexes
      14
  • Captures
    1

Article Description

The millimeter-wave spectrum of the GeF + ion in the ground vibrational state was observed for four major isotopic species. The ion was generated in a free-space absorption cell by a hollow cathode discharge in GeF 4 mixed with Ar. The magnetic field effect was used to discriminate the absorption lines of the ion from those of neutral species; the intensity of the ion lines decreased markedly on applicatin of an axial magnetic field of about 170 G. The observed millimeter-wave spectrum was combined with a previously reported diode laser spectrum in an analysis to determine mass-independent Dunham coefficients. The equilibrium bond length is r e = 1.664821 Å.

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