FTIR study of the interaction of Re 2 (CO) 10 with Na-Y zeolite
Journal of Molecular Catalysis, ISSN: 0304-5102, Vol: 70, Issue: 1, Page: 43-52
1991
- 7Citations
- 3Captures
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Article Description
The interaction of Re 2 (CO) 10 with zeolite Na-Y was studied by means of FTIR spectroscopy. Three species of supported metal carbonyl were found and assigned to (I) slightly perturbed (physisorbed) Re 2 (CO) 10 molecules, (II) Re 2 (CO) 10 O-bonded to zeolitic Na + ions via a CO ligand and (III) more perturbed Re 2 (CO) 10 molecules encaged inside the faujasite supercages. Upon thermolysis at 630 K the zeolite-supported metal carbonyl was completely decarbonylated. The remaining metal particles were detected spectroscopically by CO adsorption at room temperature.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/030451029185004L; http://dx.doi.org/10.1016/0304-5102(91)85004-l; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0026257951&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/030451029185004L; https://api.elsevier.com/content/article/PII:030451029185004L?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:030451029185004L?httpAccept=text/plain; http://linkinghub.elsevier.com/retrieve/pii/030451029185004L; http://api.elsevier.com/content/article/PII:030451029185004L?httpAccept=text/xml; http://api.elsevier.com/content/article/PII:030451029185004L?httpAccept=text/plain; http://dx.doi.org/10.1016/0304-5102%2891%2985004-l; https://dx.doi.org/10.1016/0304-5102%2891%2985004-l
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