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Effect of Hg(II) on hydrogenase activity from Desulfovibrio vulgaris (Miyazaki)

Journal of Molecular Catalysis A: Chemical, ISSN: 1381-1169, Vol: 96, Issue: 3, Page: 329-333
1995
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Article Description

Effect of Hg(II) on the intact hydrogenase activity from Desulfovibrio vulgaris (Miyazaki) was studied kinetically. When the hydrogenase was incubated with Hg(II), the hydrogen evolution rate was strongly inhibited. From the absorption spectra of the iron-sulfur cluster(s) and the EPR spectra of [3Fe4S] cluster and Ni center, reaction mechanism is discussed.

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