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Voltammetric behaviour of technetium 99 complexes with π-acceptor ligands in aprotic medium. III. Oxidation of technetium(I) complexes with phosphine and carbon monoxide ligands

Inorganica Chimica Acta, ISSN: 0020-1693, Vol: 41, Issue: C, Page: 95-98
1980
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  • Citations
    18
    • Citation Indexes
      18

Article Description

The anodic behaviour of TcCl(CO) 2 (PMe 2 Ph) 3 and TcCl(CO) 3 (PMe 2 Ph) 2 complexes has been studied in acetonitrile solvent. Both the complex undergo an overall two-electron oxidation process with the formation of Tc(III) species; the electrode mechanism leading to their formation has been studied. In particular the [TcCl(CO)(MeCN) 2 (PMe 2 Ph) 3 ][ClO 4 ] 2 compound has been isolated and characterized.

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