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Metal-organic framework-based electrocatalysts for ORR, OER, and HER

Nanomaterials for Electrocatalysis, Page: 111-144
2022
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Book Chapter Description

The tailorable properties and numerous diversified morphologies enable metal-organic frameworks (MOFs) to be utilized in a wide range of applications such as water splitting, energy storage, and fuel cells. In recent times, rational designing and synthetic techniques of various MOFs and their nanoparticle derivatives have brought a possibility to be served as an exceptional electrocatalyst for oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER). This approach results from the improved surface area, porosity, pore-volume, and tunable structure of MOF-based materials. This chapter presents the introduction of ORR, OER, and HER along with detailed sections about MOF-derived nonprecious metal-based electrocatalysts for each reaction. The structural and electrochemical characteristics for various synthetic schemes of MOF-derived materials and their comparability with platinum-based electrocatalysts have been discussed in detail. In the last sections, materials displaying multifunctionality have been addressed.

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