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Bismuth-based Lewis acidity

Advances in Inorganic Chemistry, ISSN: 0898-8838, Vol: 82, Page: 237-260
2023
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Article Description

Well-defined molecular bismuth compounds have been exploited as Lewis acids for applications in synthesis and catalysis, including element-specific reactions. This contribution aims to give an overview covering the design, assessment, and application of Lewis acidic molecular bismuth compounds. The characteristics of these Lewis acids are analyzed with respect to strength, hard vs soft character, and the number of Lewis acidic sites. The strategies that have been utilized to understand and tune the Lewis acidity of bismuth compounds are highlighted. The impact of Lewis acidity on selected stoichiometric and catalyzed reactions are presented.

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