The role of copper species on Cu/γ-Al 2 O 3 catalysts for NH 3 –SCO reaction
Applied Surface Science, ISSN: 0169-4332, Vol: 258, Issue: 8, Page: 3738-3743
2012
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Article Description
UV–vis spectra, XRD, H 2 -TPR, TEM and ESR were used to characterize a series of Cu/γ-Al 2 O 3 catalysts, which were prepared by incipient wetness impregnation using copper nitrate, copper acetate or copper sulfate as precursors, to study the role of Cu species on Cu/γ-Al 2 O 3 catalysts for NH 3 –SCO reaction. It was found that the mixture of CuO phase and CuAl 2 O 4 phase formed on various Cu/γ-Al 2 O 3 catalysts, and the Cu species and dispersion had significant influence on the Cu/γ-Al 2 O 3 activity. Highly dispersed CuO phase on the support would be related with its high activity for the NH 3 –SCO reaction.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0169433211019088; http://dx.doi.org/10.1016/j.apsusc.2011.12.017; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84856235998&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0169433211019088; https://dx.doi.org/10.1016/j.apsusc.2011.12.017
Elsevier BV
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