Electrocatalytic oxidation of dimethyl ether on ruthenium modified platinum single crystal electrodes
Catalysis Communications, ISSN: 1566-7367, Vol: 10, Issue: 6, Page: 971-974
2009
- 12Citations
- 10Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
Ruthenium were deposited on Pt( h k l ) single crystal surfaces using repeated spontaneous deposition procedure. Pt( h k l )/Ru surfaces with different Ru coverage were first applied for the electrocatalytic oxidation of dimethyl ether (DME) to clarify the structure dependence of Ru modification. Cyclic voltammograms (CVs) show that the catalytic activity after Ru modification is promoted on Pt(1 0 0) while inhibited on Pt(1 1 0) and Pt(1 1 1) surfaces. Pt(1 0 0)/Ru surface yields a higher surface activity than clean Pt(1 0 0) within a potential range from 0.60 to 0.72 V, especially after one single spontaneous deposition. Pt(1 1 0)/Ru and Pt(1 1 1)/Ru have almost no activity for DME oxidation.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1566736708005748; http://dx.doi.org/10.1016/j.catcom.2008.12.042; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=58949104578&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1566736708005748; https://dx.doi.org/10.1016/j.catcom.2008.12.042
Elsevier BV
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