High energy density flexible zinc–ion batteries enabled by polyaniline-encapsulated molybdenum-doped tungsten oxide nanorods as a zinc intercalation electrode
Chemical Engineering Journal, ISSN: 1385-8947, Vol: 474, Page: 145745
2023
- 5Citations
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Most Recent News
Researchers from Jeonbuk National University Report Details of New Studies and Findings in the Area of Nanorods (High Energy Density Flexible Zinc-ion Batteries Enabled By Polyaniline-encapsulated Molybdenum-doped Tungsten Oxide Nanorods As a ...)
2023 NOV 07 (NewsRx) -- By a News Reporter-Staff News Editor at South Korea Daily Report -- Research findings on Nanotechnology - Nanorods are discussed
Article Description
With the rising technology of flexible and wearable portable smart devices, aqueous rechargeable zinc–ion batteries (ZIBs) are one of the potential candidates as energy storage devices, however, the uncontrollable growth of Zn dendrites owing to the uneven deposition of zinc during charging, and the scarcity of high-performance electrodes limit the development of high-performance flexible ZIBs. Herein, a novel PANI@WMoO 3 nanorods (NRs) core–shell nanostructure is designed as an intercalation electrode for the development of aqueous flexible ZIBs. Advancing from a PANI buffer layer and accelerating Zn 2+ ion insertion/extraction owing to the hexagonal crystalline structure of WMoO 3, the PANI@WMoO 3 //Zn/CC battery exhibits outstanding electrochemical performance, with a high specific capacity of 329.0 mA·h/g at 0.2 A/g, exceptional rate capability, and superior cyclic stability (∼90.09 % after 1,000 cycles). In addition, the fabricated flexible ZIBs demonstrate excellent mechanical characteristics. Moreover, the ZIBs deliver a high energy density of 394.8 W·h/kg at a power density of 141.6 W/kg. Additionally, a Zn metal-free aqueous Zn-ion battery is successfully assembled with PANI@WMoO 3 NRs/CC as anode and a ZnMnO 4 as cathode, which exhibits an excellent specific capacity of 247.3 mA·h/g at 0.2 A/g, good rate capability and cyclic stability (∼94.7 % after 1,000 cycles), signifying the practicability of PANI@WMoO 3 NRs/CC as an intercalated anode for Zn 2+ ion full batteries.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1385894723044765; http://dx.doi.org/10.1016/j.cej.2023.145745; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85170035461&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1385894723044765; https://dx.doi.org/10.1016/j.cej.2023.145745
Elsevier BV
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