Evolution of high temperature oxidation properties of SiC f /SiCN composites with BN interphase

In this study, SiC/SiCN composites with BN interphase were prepared using chemical vapor infiltration (CVI) and polymer infiltration and pyrolysis (PIP) methods. The evolution and related mechanisms of mechanical and microwave absorption properties of the composites after oxidation at 800 °C, 1000 °C, 1200 °C, and 1400 °C were investigated. The results showed that with the elevating of oxidation temperature, the flexural strength of SiC/SiCN composites gradually decreased, with a retention rate of 56.7 % after oxidation at 1400 °C. The main reasons for the deterioration of mechanical properties were the changes in the crystal structure of SiC fibers under high-temperature conditions and the formation of brittle SiO 2 phases on the surface and interior of the SiCN matrix. With the increase in oxidation temperature, the microwave absorption performance of the composites showed an enhancing trend. The main reasons were that after oxidation treatment, the reduction of free carbon content and the formation of SiO 2 film layers from the oxidation of SiC and SiCN led to a decrease in the complex permittivity of the composites, resulting in better impedance matching and dielectric loss capabilities. The contributions of BN interphase to stress dispersion, interface polarization, and oxidation protection significantly enhance the mechanical and electromagnetic absorption properties of the composites. Therefore, SiC/SiCN composites are high-temperature structural microwave absorbing materials with great application prospects.