Aqueous coordination polymer complexes: From colloidal assemblies to bulk materials

1-dimensional (1D) coordination polymers refer to the macromolecules that have metal ions incorporated in their pendent groups or main chain through metal-binding ligand groups. They have intrinsic advantages over traditional polymers to regulate the polymer structures and functions owing to the nature of the metal-ligand bond. Consequently, they have great potential for the development of smart and functional structures and materials and therapeutic agents. Water-soluble 1D coordination polymers and assemblies are an important subtype of coordination polymers with distinctive interests for demanding applications in aqueous systems, such as biological and medical applications. This review highlights the recent progress and research achievements in the design and use of water-soluble 1D coordination polymers and assemblies. The overview covers the design and structure control of 1D coordination polymers, their colloidal assemblies, including nanoparticles, nanofibers, micelles and vesicles, and fabricated bulk materials such as membraneless liquid condensates, security ink, hydrogel actuators, and smart fabrics. Finally, we discuss the potential applications of several of these coordination polymeric structures and materials and give an outlook on the field of aqueous coordination polymers.