Effect of ageing in the electrolyte and water on porous anodic films on zirconium
Corrosion Science, ISSN: 0010-938X, Vol: 53, Issue: 6, Page: 2299-2305
2011
- 15Citations
- 32Captures
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Article Description
The present study demonstrates the significant influence of ageing in the formation electrolyte on the morphology and composition of anodic films grown on zirconium in 0.35 M ammonium fluoride in glycerol. Ageing after anodizing, by immersion in the electrolyte for 1 h, is shown to promote a transition from a porous to a nanotubular morphology, due to the dissolution of the fluoride-rich intratubular material in which the nanotubes are embedded. The morphological change is accompanied by a significant loss of zirconium and fluorine from the film. In contrast, ageing in deionized water has little influence on the films.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0010938X11001673; http://dx.doi.org/10.1016/j.corsci.2011.03.014; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79955023402&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0010938X11001673; https://dx.doi.org/10.1016/j.corsci.2011.03.014
Elsevier BV
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