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Effect of pretreatments on the hydrogen evolution kinetics of pure titanium using impedance and SECM technologies

Corrosion Science, ISSN: 0010-938X, Vol: 191, Page: 109726
2021
  • 24
    Citations
  • 0
    Usage
  • 11
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    24
    • Citation Indexes
      24
  • Captures
    11

Article Description

The behaviors and kinetics of hydrogen evolution reaction (HER) on pure titanium spontaneously passivated in air (P-Ti), activated by electrochemical method (EA-Ti) and fluoride ion (FA-Ti) were investigated by impedance and scanning electrochemical microscopy (SECM). During cathodic polarization, the passive film and proton were simultaneously reduced on P-Ti, only HER current was detected on EA-Ti, while both HER and active/passive transition behavior presented on FA-Ti. Corresponding transfer coefficients and standard rate constants of HER are 0.48/6.00 × 10 −12 cm/s, 0.25/7.60 × 10 −7 cm/s and 0.24/1.14 × 10 −6 cm/s, respectively. These differences originate from the change in electronic structure of passive film by pretreatments.

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