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Carburization behavior of FeCrAl alloy APMT and the critical role of pre-oxidation

Corrosion Science, ISSN: 0010-938X, Vol: 224, Page: 111520
2023
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Article Description

The carburization behavior of bare and pre-oxidized APMT has been assessed after long-term graphite exposure at 1000 °C. Bare coupons formed a thick scale after graphite exposure due to carbon interaction and chromium-rich carbides were detected, as predicted from thermodynamic calculations. Pre-oxidation of APMT was conducted in air, and oxidation kinetics were measured through thermogravimetry. The oxide layer formed at 800 °C failed to prevent carburization. However, increasing the pre-oxidation temperature to 1200 °C produced an oxide layer with good resistance to carbon diffusion indicating that the alpha-alumina formed at high temperatures is key in preventing carburization of the material.

Bibliographic Details

Maria Kosmidou; Thomas J. Nizolek; Jason T. Rizk; Kim Hyosim; Erik P. Luther; Anthony Schroeder; Jurie Van Wyk; Christopher Matthews; Erofili Kardoulaki

Elsevier BV

Chemistry; Chemical Engineering; Materials Science

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