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Quantum control of spin–orbit coupling by dynamic Stark-shifts induced by laser fields

Chemical Physics Letters, ISSN: 0009-2614, Vol: 431, Issue: 4, Page: 231-235
2006
  • 40
    Citations
  • 0
    Usage
  • 11
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    40
    • Citation Indexes
      40
  • Captures
    11

Article Description

We show that electronic states can be decoupled, removing the crossing between the potentials, or coupled, inducing intramolecular crossings, by applying dynamic Stark-shifts with strong nonresonant pulses. As an example, stopping and enhancing the singlet–triplet transfer between the 1 1 Σ u and 1 3 Π u excited states to create purified spin states in the Rb 2 molecule is demonstrated.

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