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Ionization of water in interfacial electric fields: An electrochemical view

Chemical Physics Letters, ISSN: 0009-2614, Vol: 519, Page: 1-17
2012
  • 122
    Citations
  • 0
    Usage
  • 140
    Captures
  • 2
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    122
    • Citation Indexes
      120
    • Patent Family Citations
      1
      • Patent Families
        1
    • Policy Citations
      1
      • Policy Citation
        1
  • Captures
    140
  • Mentions
    2
    • References
      2
      • Wikipedia
        2

Article Description

High electric fields promote ionization of water, yet relatively little is known about this topic due to the difficulty of generating such fields. The high field capability of field emitter tips enables study of ionization in water layers. Results from this work include ionization fields, water layer morphology, dielectric properties, coadsorbate interactions, cluster distributions of hydrated hydronium ions H + (H 2 O) m, and field ionization images. These experimental results, combined with theoretical findings, are interpreted in the context of four examples from electrochemistry; double layer structure, hydrogen oxidation, CO oxidation, and oxygen reduction; to reveal the research frontier in interfacial ionization of water.

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