Two-photon excitations of the Cs 2 33Σg+ state: Assignment and analysis with the deformed ab initio potential
Chemical Physics Letters, ISSN: 0009-2614, Vol: 557, Page: 66-70
2013
- 6Citations
- 8Captures
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Article Description
One color two-photon 33Σg+←b3Πu∼A1Σu+←X1Σg+ transitions of Cs 2 observed earlier [9] have been assigned: the upper state levels span the range of the vibrational and rotational quantum numbers v=2∼9 and N=25∼248. The potential function of the 33Σg+ state in a version of a deformed ab initio potential has been determined from the term values of these levels. The reliability of this potential is confirmed by simulations of the spectra of resolved fluorescence and by comparing with the Rydberg–Klein–Rees potential obtained from an alternative set of data in [13].
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0009261412014510; http://dx.doi.org/10.1016/j.cplett.2012.12.030; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84872896417&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0009261412014510; https://dx.doi.org/10.1016/j.cplett.2012.12.030
Elsevier BV
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