Effect of temperature and O 2 pressure on the gaseous species produced during combustion of aluminum
Chemical Physics Letters, ISSN: 0009-2614, Vol: 649, Page: 88-91
2016
- 8Citations
- 12Captures
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Article Description
Effect of temperature and O 2 pressure on the gaseous species produced during the combustion of aluminum is studied using first principles calculations and considering the thermodynamics of the gas phase equilibrium composed of Al, O 2, AlO, Al 2 O, AlO 2, Al 2 O 2 and Al 2 O 3. AlO partial pressure dominates all the range of O 2 pressures/temperatures. AlO 2 is the second most abundant species at low to intermediate temperatures (1200⿿1727 °C) and Al 2 O at higher temperatures (⿼3300 °C). Al 2 O and Al 2 O 2 are stable when ionized into mass spectrometer. Al 2 O 3, AlO 2 and, to a lesser extent AlO, will decompose, hindering their quantitative observation using this technique.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0009261416300756; http://dx.doi.org/10.1016/j.cplett.2016.02.048; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84961584094&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0009261416300756; https://api.elsevier.com/content/article/PII:S0009261416300756?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0009261416300756?httpAccept=text/plain; https://dul.usage.elsevier.com/doi/; https://dx.doi.org/10.1016/j.cplett.2016.02.048
Elsevier BV
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