High pressure studies of potassium perchlorate
Chemical Physics Letters, ISSN: 0009-2614, Vol: 660, Page: 37-42
2016
- 15Citations
- 17Usage
- 14Captures
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Metrics Details
- Citations15
- Citation Indexes15
- 15
- CrossRef8
- Usage17
- Abstract Views17
- Captures14
- Readers14
- 14
Article Description
Two experiments are reported on KClO 4 at extreme conditions. A static high pressure Raman study was first conducted to 18.9 GPa. Evidence for at least two new phases was observed: one between 2.4 and 7.7 GPa (possibly sluggish), and the second near 11.7 GPa. Then, the X-ray induced decomposition rate of potassium perchlorate KClO4→hνKCl+2O2 was studied up to 15.2 GPa. The time-dependent growth of KCl and O 2 was monitored. The decomposition rate slowed at higher pressures. We present the first direct evidence for O 2 crystallization at higher pressures, demonstrating that O 2 molecules aggregate at high pressure.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0009261416305516; http://dx.doi.org/10.1016/j.cplett.2016.07.060; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84980008608&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0009261416305516; https://api.elsevier.com/content/article/PII:S0009261416305516?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0009261416305516?httpAccept=text/plain; https://dul.usage.elsevier.com/doi/; https://digitalscholarship.unlv.edu/physastr_fac_articles/82; https://digitalscholarship.unlv.edu/cgi/viewcontent.cgi?article=1081&context=physastr_fac_articles; https://dx.doi.org/10.1016/j.cplett.2016.07.060
Elsevier BV
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