Benzobisthiazole and rhodanine based low energy level small molecule donors for organic solar cells
Dyes and Pigments, ISSN: 0143-7208, Vol: 234, Page: 112564
2025
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Findings from Ocean University of China Update Knowledge of Organic Solar Cells (Benzobisthiazole and Rhodanine Based Low Energy Level Small Molecule Donors for Organic Solar Cells)
2025 MAR 04 (NewsRx) -- By a News Reporter-Staff News Editor at Tech Daily News -- Data detailed on Solar Cells - Organic Solar Cells
Article Description
At present, high-performance small molecule donors for organic solar cells (OSCs) are almost entirely composed of the electron donating core benzodithiophene (BDT), which has resulted in a lack of material diversity and further improvement. In this article, we constructed an A-π-A′-π-A conjugated structure using electron withdrawing group benzobisthiazole (BBT) core and rhodanine end group, and synthesized two small molecule donors BBTSM-3 and BBTSM-4. Under the dual electron withdrawing effects of BBT and rhodanine, the HOMO energy levels of BBTSM-3 and BBTSM-4 reached extremely low levels (−5.60 eV and −5.64 eV), but still matched well with the acceptor Y6. In addition, through reasonable side chain regulation, BBTSM-3 exhibited stronger crystallinity and weaker aggregation at the same time. This provides a reference point for the use of the electron withdrawing core and the regulation of side chains among small molecule donors.
Bibliographic Details
Elsevier BV
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