Correlations between hydrogen electrosorption properties and composition of Pd-noble metal alloys
Electrochemistry Communications, ISSN: 1388-2481, Vol: 9, Issue: 4, Page: 671-676
2007
- 33Citations
- 17Captures
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Article Description
Hydrogen adsorption on and absorption into Pd alloys with other noble metals was studied in acidic solutions (0.5 M H 2 SO 4 ) using cyclic voltammetry. Correlations were found between the potentials of adsorbed/absorbed hydrogen oxidation peaks and surface/bulk compositions of Pd–Rh alloys. The potential of the α–β-phase transition depends linearly on Pd bulk content in Pd–Au, Pd–Rh, Pd–Pt and Pd–Pt–Rh alloys. The obtained relationships can be utilized for the determination of the composition of homogeneous Pd-noble alloys from hydrogen electrosorption experiments.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1388248106005121; http://dx.doi.org/10.1016/j.elecom.2006.10.055; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33947718110&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1388248106005121; https://dx.doi.org/10.1016/j.elecom.2006.10.055
Elsevier BV
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