Extraordinarily small Tafel slope for oxide formation reaction on Pt (1 1 1) surface
Electrochimica Acta, ISSN: 0013-4686, Vol: 78, Page: 592-596
2012
- 19Citations
- 39Captures
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Article Description
Oxide formation reaction current density on Pt (1 1 1) was estimated by time-differentiating oxide growth curves during a potential hold as a function of the potential and the coverage with the oxide below 0.35 ML (monolayer). The Tafel slope was 18–24 mV decade −1 in the condition where the Tafel plot is on a straight line. The reaction mechanism accounting for this small slope was proposed, in which the oxide formation process is assumed as a combination of a fast electron transfer step and a following slow step.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0013468612010365; http://dx.doi.org/10.1016/j.electacta.2012.06.061; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84864290226&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0013468612010365; https://dul.usage.elsevier.com/doi/; https://api.elsevier.com/content/article/PII:S0013468612010365?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0013468612010365?httpAccept=text/plain; https://dx.doi.org/10.1016/j.electacta.2012.06.061
Elsevier BV
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