PlumX Metrics
Embed PlumX Metrics

Highly efficient visible-light-driven photocatalytic degradation of organic pollutants by using magnetically separable supported heterogeneous nanocomposites (SiO 2 /Fe 3 O 4 /Ag 2 WO 4 )

Environmental Nanotechnology, Monitoring & Management, ISSN: 2215-1532, Vol: 16, Page: 100554
2021
  • 37
    Citations
  • 0
    Usage
  • 40
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    37
    • Citation Indexes
      37
  • Captures
    40

Article Description

In this work, the heterogeneous photocatalyst (SiO 2 /Fe 3 O 4 /Ag 2 WO 4 ) that is composed of active nanomaterials precipitated onto mesoporous nanosilica was synthesized using multistep methods. The nanosilica was synthesized using the Stöber method. 10% Wt. of Fe 3 O 4 and Ag 2 WO 4 NPs were precipitated on the surface of nanosilica to produce supported SiO 2 /Fe 3 O 4 /Ag 2 WO 4 magnetic nanoparticles (MNPs). Different techniques were used to characterize the synthesized supported MNPs, including UV-DRS, XRD, VSM, BET, BJH, and FE-SEM. The photocatalytic degradation activity of synthesized supported MNPs was conducted through a batch reactor towards methylene blue dye (M.B) under visible light irradiation (40 W LED and 55 W Xenon lamps). The experimental results showed a high degradation efficiency (approximately 100%) related to SiO 2 /Fe 3 O 4 /Ag 2 WO 4 after 45 min of irradiation time. The SiO 2 /Fe 3 O 4 /Ag 2 WO 4 revealed high adsorption activity, where 60% of its removal efficiency was during the first 60 min of adsorption in the dark. The kinetics studies revealed that the photocatalytic activity of SiO 2 /Fe 3 O 4 /Ag 2 WO 4 was nearly 4.2 and 3.9 times higher than pure Ag 2 WO 4 and SiO 2 /Fe 3 O 4, respectively. The significantly improved photocatalytic activity of the SiO 2 /Fe 3 O 4 /Ag 2 WO 4 MNPs was attributed to their higher stability and specific surface area, in addition to a synergistic outcome between Ag 2 WO 4 and SiO 2 /Fe 3 O 4 that leads to efficient electron–hole pairs separation. The effects of several parameters were also examined for supported MNPs, including catalyst dose, initial concentration of M.B, pH, and H 2 O 2 addition. The reusability and recyclability study revealed that the synthesized SiO 2 /Fe 3 O 4 /Ag 2 WO 4 are highly stable and can be used with high feasibility for removal of different organic dyes from wastewater.

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know