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Electrochemical difunctionalization of isocyanides by a three-component reaction cascade Mumm rearrangement: Rapid access to sulfur-containing imides

Green Synthesis and Catalysis, ISSN: 2666-5549
2024
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Article Description

An efficient and practical electrochemical method for the three-component reaction cascade Mumm rearrangement of imides has been developed using a simple undivided cell with carbon electrodes at room temperature, which provides a useful strategy for the rapid synthesis of sulfur-containing imides with broad substrate scope and high functional tolerance. It is a rare example of in situ generation of O -acyl isoamide precursor for Mumm rearrangement.

Bibliographic Details

Hongmei Jiang; Zhibin Nong; Xi Chen; Tiancheng Cai; Hanxuan Zhang; Rui Li; Qiang Li; Lei Liu; Qing-Wen Gui

Elsevier BV

Biochemistry, Genetics and Molecular Biology; Chemical Engineering

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