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Two chemically robust coordination polymers as fluorescent probes for effective sensing of sulfadiazine/ornidazole and Cd 2+ ions

Inorganica Chimica Acta, ISSN: 0020-1693, Vol: 550, Page: 121449
2023
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Two new ternary Cd(II) coordination polymers (CPs), namely [Zn(bdc)(L)] n ( 1 ) and {[Cd(bta) 0.5 (L)]·H 2 O} n ( 2 ) (H 2 bdc = 1,4-dicarboxybenzene, H 4 bta = 1,2,4,5-benzenetetracarboxylic acid, and L = 1,6-bis(benzimidazol-2-yl)hexane) were synthesized through the hydrothermal reactions. 1 displays a 1D infinite chain while 2 reveals a 3D moganite ( mog ) network. The as-prepared functionalized 1 / 2 exhibit remarkable thermal and chemical stabilities. The two CPs can be utilized as the dual fluorescence chemosensors for the detection of sulfadiazine (SDZ)/Cd 2+ (for 1 ) and ornidazole (ORN)/Cd 2+ (for 2 ) through fluorescence quenching effect with high sensitivity and selectivity.

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