Interpenetrating and semi-interpenetrating network superabsorbent hydrogels based on sodium alginate and cellulose nanocrystals: A biodegradable and high-performance solution for adult incontinence pads

Superabsorbent hydrogels (SAHs) are essential in various applications, including hygienic products like adult incontinence pads. However, synthetic-based super absorbent polymers (SAPs) dominate the market despite being non-biodegradable. Alternatively, bio-based hydrogels, such as sodium alginate (SA)-based hydrogels, offer biodegradable alternatives. In this study, we aimed to enhance the practical applied properties of SA-based hydrogels by grafting SA with acrylic acid (AA) and incorporating cellulose nanocrystals (CNCs). Specifically, we investigated the potential of interpenetrating network (IPN) and semi-interpenetrating network (S-IPN) hydrogels as absorbent materials in adult incontinence pads. The fabricated SAHs were characterized by Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). They were also evaluated for absorption and rheological properties. The results showed that in IPN/SAHs, the addition of CNCs decreased pore sizes, while in S-IPN/SAHs, CNC incorporation increased pore sizes. The S-IPN/SAHs exhibited a significantly higher free swelling capacity (FSC) with CNCs loading, reaching 142.29 g/g in 0.9 % NaCl solution and 817.4 g/g in distilled water. On the other hand, IPN/SAHs showed a higher storage modulus and lower loss modulus compared to S-IPN/SAHs. Notably, the superior samples from this study showed a 33 % reduction in SAP consumption compared to commercial SAPs, making them more cost-effective for adult incontinence pad manufacturers. Overall, our research demonstrates the potential of interpenetrating and semi-interpenetrating network superabsorbent hydrogels as high-performance absorbent materials. The results offer improved absorbency and cost savings for producers of adult incontinence pads, and bio-based hydrogels like SA-based hydrogels are promising biodegradable alternatives to synthetic-based SAPs.