Numerical simulation and experimental study of hydrogen production from chili straw waste gasification using Aspen Plus

Biomass gasification is a promising method for hydrogen production. This study systematically models the gasification of chili straw waste (CSW) using the Aspen Plus simulator, focusing on the effects of gasification agents—steam, air, and oxygen—and sensitivity analyses of key parameters. Results show that under optimal steam gasification conditions, with a temperature of 700 °C and atmospheric pressure, hydrogen concentration reached 59.61%, while the lower heating value (LHV) decreased to 6.65 MJ/m 3 due to CO reduction. In air gasification, increasing air input reduced hydrogen and CO concentrations by 18.5% and 26.6%, respectively, while LHV dropped by 52.5%. Oxygen-enriched gasification significantly improved hydrogen and CO concentrations, increasing LHV by 129.4% as the oxygen fraction rose. Sensitivity analysis revealed that optimal hydrogen production in air-steam gasification occurred with a low equivalence ratio of 0.18, moderate temperature around 700 °C, and atmospheric pressure. These findings highlight the critical role of temperature, pressure, and gasifying agents in optimizing hydrogen production, providing a basis for improving the efficiency of biomass gasification systems.