A novel [Dy 4 (OH) 4 ]-based porous coordination polymer with double-wall structure: Topology structure, fluorescence and magnetic properties
Inorganic Chemistry Communications, ISSN: 1387-7003, Vol: 127, Page: 108531
2021
- 3Citations
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations3
- Citation Indexes3
- CrossRef1
Article Description
A novel [Dy 4 (OH) 4 ]-based porous coordination polymer with double-wall structure, [Dy(OH)(cppc)] n ( 1 ) (H 2 cppc = 5-(4-carboxyphenyl)pyridine-2-carboxylic acid), has been successfully obtained through solvo-thermal method and characterized by elemental analysis, IR spectrum, powder X-ray diffraction, single-crystal X-ray diffraction and thermal analysis. Structure analysis shows compound 1 is a three-dimensional porous coordination polymer with double-wall structure constructed by [Dy 4 (OH) 4 ] 8+ cubane-like units and (cppc) 2− anions, in which one-dimensional square channels with the dimensions 11.78 × 11.78 Å 2 are observed. Topology analysis reveals compound 1 has an unprecedented (3, 12)-connected topology net with Schlafli symbol {4 20.6 28.8 18 }{4 3 } 4. Thermal analysis indicates the framework of compound 1 kept thermally stable until 370 °C. Fluorescent experiment indicates that compound 1 show apparently blue light emission in the solid state. Variable-temperature magnetic susceptibility measurement indicates strong antiferromagnetic interactions in [Dy 4 (OH) 4 ] 8+ SBU for compound 1.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1387700321000903; http://dx.doi.org/10.1016/j.inoche.2021.108531; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85102345235&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1387700321000903; https://dx.doi.org/10.1016/j.inoche.2021.108531
Elsevier BV
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