Why silver is the unique catalyst for ethylene epoxidation
Journal of Catalysis, ISSN: 0021-9517, Vol: 284, Issue: 2, Page: 230-235
2011
- 102Citations
- 133Captures
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
The activities of Cu 2 O(0 0 1), Ag 2 O(0 0 1), and Au 2 O(0 0 1) surfaces for direct ethylene epoxidation and alternative paths for EO isomerization are studied. Among these three oxide surfaces, only Ag 2 O(0 0 1) surface enables direct path without a barrier. Au 2 O cannot regenerate surface oxygen, and overall reaction on Cu 2 O is endothermic. Furthermore, ring opening of ethylene oxide (EO) and subsequent acetaldehyde (AA) formation on Cu 2 O is more favorable than EO desorption. Ethylene adsorption on an oxygen vacancy results in the oxametallacycle (OMC) formation, which causes AA formation and reduces EO selectivity. Cl adsorption removes these surface vacant sites and hence prevents the formation of the OMC intermediate.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0021951711002466; http://dx.doi.org/10.1016/j.jcat.2011.08.004; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=82255174960&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0021951711002466; https://api.elsevier.com/content/article/PII:S0021951711002466?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0021951711002466?httpAccept=text/plain; https://dx.doi.org/10.1016/j.jcat.2011.08.004
Elsevier BV
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know